53

Chemical and elemental mapping of spent nuclear fuel sections by soft X-ray spectromicroscopy

A. S. Ditter, D. E. Smiles, D. Lussier, A. B. Altman, M. Bachhav, L. He, M. W. Mara, C. Degueldre, S. G. Minasian, D. K Shuh*

J. Synchro. Rad., 2022, 29, 67-79. DOI: 10.1107/S1600577521012315

52

Involvement of 5f Orbitals in the Covalent Bonding between the Uranyl Ion and Trialkyl Phosphine Oxide: Unraveled by Oxygen K-Edge X-ray Absorption Spectroscopy and Density Functional Theory

Yusheng Zhang, Wuhua Duan, Yuning Yang, Tian Jian, Yusen Qiao, Guoxi Ren, Nian Zhang, Lei Zheng, Wensheng Yan, Jianchen Wang, Jing Chen, Stefan G. Minasian, and Taoxiang Sun*

Inorg. Chem., 2021, ASAP Article. DOI: 10.1021/acs.inorgchem1c02236

51

A Uranium(II) Arene Complex That Acts as a Uranium(I) Synthon

Mark D. Straub, Erik T. Ouellette, Michael A. Boreen, R. David Britt, Khetpakorn Chakarawet, Iskander Douair, Colin A. Gould, Laurent Maron, Iker Del Rosal, David Villarreal, Stefan G. Minasian,* and John Arnold*

J. Am. Chem. Soc. 2021. Accepted Manuscript. DOI: 10.1021/jacs.1c07854

50

Enhanced 5f-δ bonding in [U(C₇H₇)₂]⁻: Carbon K‑Edge X‑ray Spectroscopy, Magnetism and Electronic Structure Calculations

Yusen Qiao, Gaurab Ganguly, Corwin H. Booth, Jacob A. Branson, Alexander S. Ditter, Daniel J. Lussier, Liane M. Moreau, Dominic Russo, Dumitru-Claudiu Sergentu, David K. Shuh, Taoxiang Sun, Jochen Autschbach,* and Stefan G. Minasian*

Chem. Comm. 2021, 57, 9562-9565. DOI: 10.1039/D1CC03414F

49

Thorium amidates function as single-source molecular precursors for thorium dioxide

M. D. Straub, E. T. Ouellette, M. A. Boreen, J. A. Branson, A. Ditter, A. L. D. Kilcoyne, T. D. Lohrey, M. A. Marcus, M. Paley, J. Ramirez, D. K. Shuh, S. G. Minasian*, J. Arnold*

Chem. Comm. 2021, 57, 4954-4957. DOI: 10.1039/D1CC00867F

48

Amidinate Supporting Ligands Influence Molecularity in Formation of Uranium Nitrides

M. D. Straub, L. M. Moreau, Y. Qiao, Erik T. Ouellette, M. A. Boreen, T. D. Lohrey, N. S. Settineri, S. Holoch, C. H. Booth, S. G. Minasian*, John Arnold*

Inorg. Chem. 2021, 60, 9, 6672–6679. DOI: 10.1021/acs.inorgchem.1c00471

25

Energy-Degeneracy Driven Covalency in Actinide Bonding

J. Su, E. R. Batista*, S. E. Bone, K. S. Boland. J. A. Bradley, S. K. Cary, D. L. Clark*, S. D. Conradson, A. S. Ditter, J. M. Keith, A. Kerridge, M. W. Loeble, R. L. Martin, S. G. Minasian, V. Mocko, H. S. La Pierre, N. Kaltsoyannis, S. A. Kozimor*, M. P. Wilkerson, L. E. Wolfsberg, G. T. Seidler, D. K. Shuh, and P. Yang*

J. Am. Chem. Soc. 2018, 140, 17977-17984. DOI: 10.1021/jacs.8b09436

24

Electron localization in a mixed-valence diniobium benzene complex

T. L. Gianetti, G. Nocton, S. G. Minasian, N. Kaltsoyannis*, A. L. D. Kilcoyne, S. A. Kozimor, D. K. Shuh, T. Tyliszczak, R. G. Bergman* and J. Arnold*

Chem. Sci. 2015, 6, 993-1003. DOI: 10.1039/c4sc02705a

23

Synthesis and characterization of eight compounds of the MU₈Q₁₇ Family: ScU₈S₁₇, CoU₈S₁₇, NiU₈S₁₇, TiU₈Se₁₇, CrU₈Se₁₇, CoU₈Se₁₇, NiU₈Se₁₇

M. D. Ward, A. Mesbah, S. G. Minasian, D. K. Shuh, T. Tyliszczak, M. Lee, E. S. Choi, S. Lebegue and J. A. Ibers*

Inorg. Chem. 2014, 53, 6920-6927. DOI: 10.1021/ic500721d

22

Electronic structure and O K-edge X-ray absorption spectroscopy of U₃O₈

X.-D. Wen, M. W. Löeble, E. R. Batista, E. Bauer, K. S. Boland, A. K. Burrell, S. D. Conradson, S. R. Daly, S. A. Kozimor*, S. G. Minasian, R. L. Martin, T. M. McCleskey, B. L. Scott, D. K. Shuh and T. Tyliszczak

J. Elec. Spec. Rel. Phenom. 2014, 194, 81-87. DOI: 10.1016/j.elspec.2014.03.005

21

Influence of pyrazolate vs N-heterocyclic carbene ligands on the slow magnetic relaxation of homoleptic trischelate lanthanide(III) and uranium(III) Complexes

K. R. Meihaus, S. G. Minasian, W. W. Lukens, Jr., S. A. Kozimor, D. K. Shuh, T. Tyliszczak and J. R. Long*

J. Am. Chem. Soc. 2014, 136, 6056-6068. DOI: 10.1021/ja501569t